Problem Guide · High Temperature Corrosion

High-Temperature Corrosion and Oxidation

On boiler and furnace surfaces, hot gas, ash and chlorine-sulphur compounds in the fuel chemically consume the metal. When erosion is also present, wall thinning accelerates sharply.

Boiler surface protected against high-temperature corrosion
How to Recognise It

Symptoms

  • Thick, layered, easily spalling oxide and ash deposits
  • Uniform or pitted wall loss under the deposit
  • Rapidly increasing tube failures in biomass and waste-fired boilers
  • Local damage at weld seams and transition zones
Where It Occurs

Typical Parts

Superheater and economiser tubesMembrane wallsRecovery boilersBiomass and waste incineration boilersIn-furnace supportsExhaust and hot gas ducts
Why It Happens

Chlorine and alkali salts in the fuel form low-melting deposits that break down the protective oxide layer and continuously consume the metal. Sulphur compounds cause sulphidation. The rate rises steeply with temperature.

Solution Options

Which Process for Which Case?

Temperature, fuel chemistry and whether the work must be done on site determine the choice.

SolutionMaterial SystemTypical ThicknessWhen Is It the Right Choice?
Arc spray (on site)Ni-Cr and Ni-based alloy wires0.3–1 mmLarge boiler surfaces, fast on-site application during outages
HVOFCr₃C₂-NiCr, Ni-based alloys150–350 µmTubes and parts that can be coated in the workshop; erosion + corrosion together
Ceramic sealer / densifierCeramic-based sealingThin filmLimits ingress of the environment through the pores of metallic coatings
Weld overlayNi-based (Inconel-type) filler1.5–3 mmMost severe corrosion zones; when a metallurgical bond is required

Values are typical ranges; the final choice is made after the part, base material and operating conditions have been seen.

Expert Note

If the fuel changed, the coating plan must change too

In plants switching from coal to biomass or waste fuel, the corrosion mechanism changes completely. A coating that worked before may be insufficient with the new fuel. Ash analysis and thickness measurements from recent outages are very useful for coating selection.

Related Content
Frequently Asked Questions

FAQ

How can tube life be extended in a biomass boiler?

Critical zones are identified by wall thickness measurement and protected with Ni-Cr based thermal spray or weld overlay. If required, pores are closed with a ceramic sealer.

Does coating reduce heat transfer?

Thin metallic coatings have a limited effect on heat transfer. Thick ash and oxide layers usually reduce heat transfer far more.

How long an outage does on-site work need?

It depends on the area and scaffolding. With measurements and photos we prepare a work schedule that fits your outage plan.

Talk Directly to an Engineer

Let’s Talk About Your Part

Take a photo of the damaged area and send it by e-mail or WhatsApp, or call us directly. On the phone we identify the mechanism together and give a suitable process and a rough cost/lead-time indication in the same call.

  1. Close-up and overall photo of the damaged area
  2. Diameter / length or a technical drawing
  3. Operating conditions: temperature, medium, particles, speed